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Discussion (27 Comments)Read Original on HackerNews
> "Initially, we did not believe it because the prevailing view is that Mn impairs the corrosion resistance of stainless steel. Mn-based passivation is a counter-intuitive discovery, which cannot be explained by current knowledge in corrosion science. However, when numerous atomic-level results were presented, we were convinced. Beyond being surprised, we cannot wait to exploit the mechanism," said Dr. Kaiping Yu, the first author of the article, whose PhD is supervised by Professor Huang.
This is the Cannot be explained bit
The three stooges effect I see. Too many corrosive elements, they stop each other from getting through the door.
The limiting factor is that natural gas is very cheap and cracking it to make blue hydrogen is really easy at scale, and gives off CO2 which is useful for injection into wells to increase production. That sets a price ceiling of hydrogen.
At the other end of the scale, there are batteries to store 'free' electricity and resell later. That sets a floor price of electricity.
Between the floor price of the input and ceiling price of the output, there is no room for electrolysis, even at 100% efficiency, unless government policies mandate it or restrict batteries or blue hydrogen.
Yes, but I think this the most likely outcome. Natural gas is only cheap in certain areas, and the past few years have made everyone very, very aware of the geopolitics involved in getting hold of it. While global warming is not going away, and I question the extent to which CCS actually happens with blue hydrogen.
Batteries are capital equipment in the same way as electrolysers are. They're great at short term storage, but medium-term is still a bit more of an issue. "Restrict batteries" is obviously not on the table except for stupid retail corner cases where utilities have captured the regulator.
There's a potential market for lots of green H2 in Haber nitrogen, metals refining, and synthetic jet fuel etc, but only if the cheap CO2 emitting option is priced out or banned, or H2 electrolysers get comparable capital prices to battery storage.
"Natural gas at Texas’s Waha hub is trading at negative $7.05 per million British Thermal Units, hitting a record low of negative $9.52 on April 15."
https://www.barrons.com/articles/natural-gas-texas-negative-...
There are different kinds of water electrolysis equipment, with different capital expenditure and operating expenses.
"Alkaline electrolyzers are cheaper in terms of investment (they generally use nickel catalysts), but least efficient. PEM electrolyzers are more expensive (they generally use expensive platinum-group metal catalysts) but are more efficient and can operate at higher current densities, and can, therefore, be possibly cheaper if the hydrogen production is large enough."
https://en.wikipedia.org/wiki/Electrolysis_of_water#Efficien...
Anything using platinum-group metals will be very expensive. Therefor catalytic converters in cars use very little platinum-group metals.
"The amount of palladium in a converter can vary, but it is typically around 2-7 grams." https://vehiclefreak.com/how-much-palladium-is-in-a-catalyti...
Now, yes, as long as natural gas is cheap(inbetween US or Soviet wars) it'll probably be the core for hydrogen, however batteries won't help much in the north since the transmission rather than usage is the cap even with batteries so excess production could be redirected towards hydrogen production.
If this works out at scale (lots of problems can be found between a lab discovery and mass production), this is legitimately a very good thing for renewables.
Splitting water into free hydrogen and oxygen is important because it is an essential step for using electrical energy in the chemical and metallurgic industries.
For long term energy storage, free hydrogen is not a good solution, but it can be used to synthesize hydrocarbons, which are suitable for long term energy storage or for aerospace transportation.
Even with abundant and cheap dihydrogen, using it for energy storage in vehicles is a bad idea.
Uh, dumb question, how is 1.7 volts "ultra high potential" ? Is that even enough to do electrolysis like they're talking about?
"Hong Kong researchers develop corrosion-resistant steel for seawater hydrogen electrolysis"